Evolution of Particle-Scale Dynamics in an Aging Clay Suspension

Evolution of particle-scale dynamics in an aging clay suspension.

Multispeckle x-ray photon correlation spectroscopy was employed to characterize the slow dynamics of a suspension of highly charged, nanometer-sized disks. At wave vectors q corresponding to interparticle length scales, the dynamic structure factor follows a form f(q,t) approximately exp([-(t/tau)(beta)], where beta approximately 1.5. The relaxation time tau increases with the sample age t(a) a...

Dynamic Evolution of Droplet/Particle Size Distribution in Suspension Polymerization of Styrene

Dissipative Particle Dynamics simulation hydrated Nafion EW 1200 as fuel cell membrane in nanoscopic scale

The microphase separation of hydrated perfluorinated sulfonic acid membrane Nafion was investigated using Dissipative Particle Dynamics (DPD). The nafion as a polymer was modelled by connecting coarse grained beads which corresponds to the hydrophobic backbone of polytetrafluoroethylene and perfluorinated side chains terminated by hydrophilic end particles of sulfonic acid groups [1, 2]. Each f...

Routes to gelation in a clay suspension.

The gelation of water suspension of a synthetic clay (Laponite) has been studied by dynamic light scattering in a wide range of clay weight concentration (C(w)=0.003-0.031). At variance with previous determination, indicating a stable liquid phase for C(w)<C(*)(w) approximately 0.015-0.018, we find that gelation actually takes place in the whole examined C(w) range. We find also that C(*)(w) ma...

Scale-invariant Gravity: Particle Dynamics

A new and universal method for implementing scale invariance, called best matching, is presented. It extends to scaling the method introduced by Bertotti and the author to create a fully relational dynamics that satisfies Mach’s principle. The method is illustrated here in the context of non-relativistic gravitational particle dynamics. It leads to far stronger predictions than general Newtonia...